Friday, 21 March 2014

Scientists Discover Potential Way to Make Graphene Superconducting

                                                                                                                                                                                      
Adding calcium atoms (orange spheres) between graphene planes (blue honeycomb) creates a superconducting material called CaC6. Now a study at SLAC has shown for the first time that graphene is a key player in this superconductivity: Electrons scatter back and forth between the graphene and calcium layers, interact with natural vibrations in the material's atomic structure and pair up to conduct electricity without resistance.

                   The researchers saw how electrons scatter back and forth between graphene and calcium, interact with natural vibrations in the material’s atomic structure and pair up to conduct electricity without resistance. They reported their findings March 20 in Nature Communications.
Graphite Meets Calcium
Graphene, a single layer of carbon atoms arranged in a honeycomb pattern, is the thinnest and strongest known material and a great conductor of electricity, among other remarkable properties. Scientists hope to eventually use it to make very fast transistors, sensors and even transparent electrodes.
The classic way to make graphene is by peeling atomically thin sheets from a block of graphite, a form of pure carbon that’s familiar as the lead in pencils. But scientists can also isolate these carbon sheets by chemically interweaving graphite with crystals of pure calcium. The result, known as calcium intercalated graphite or CaC6, consists of alternating one-atom-thick layers of graphene and calcium.
The discovery that CaC6 is superconducting set off a wave of excitement: Did this mean graphene could add superconductivity to its list of accomplishments? But in nearly a decade of trying, researchers were unable to tell whether CaC6’s superconductivity came from the calcium layer, the graphene layer or both.
Observing Superconducting Electrons
For this study, samples of CaC6 were made at University College London and brought to SSRL for analysis.
“These are extremely difficult experiments,” said Patrick Kirchmann, a staff scientist at SLAC and SIMES. But the purity of the sample combined with the high quality of the ultraviolet light beam allowed them to see deep into the material and distinguish what the electrons in each layer were doing, he said, revealing details of their behavior that had not been seen before.
“With this technique, we can show for the first time how the electrons living on the graphene planes actually superconduct,” said SIMES graduate student Jonathan Sobota, who carried out the experiments with Yang. “The calcium layer also makes crucial contributions. Finally we think we understand the superconducting mechanism in this material.”
Although applications of superconducting graphene are speculative and far in the future, the scientists said, they could include ultra-high frequency analog transistors, nanoscale sensors and electromechanical devices and quantum computing devices.
The research team was supervised by Zhi-Xun Shen, a professor at SLAC and Stanford and SLAC’s advisor for science and technology, and included other researchers from SLAC, Stanford, Lawrence Berkeley National Laboratory and University College London. The work was supported by the DOE’s Office of Science, the Engineering and Physical Sciences Research Council of UK and the Stanford Graduate Fellowship program.
SLAC is a multi-program laboratory exploring frontier questions in photon science, astrophysics, particle physics and accelerator research. Located in Menlo Park, Calif., SLAC is operated by Stanford University for the U.S. Department of Energy's Office of Science.






source:   DOE/SLAC National Accelerator