Researchers at Penn State and Shinshu University
in Japan have developed a simple, scalable method of making graphene oxide (GO)
fibers that are strong, stretchable and can be easily scrolled into yarns with
strengths approaching that of Kevlar.
The researchers made a thin film of graphene
oxide by chemically exfoliating graphite into graphene flakes, which were then
mixed with water and concentrated by centrifugation into a thick slurry. The
slurry was then spread by bar coating – something like a squeegee – across a
large plate. When the slurry dries, it becomes a large-area transparent film
that can be carefully lifted off without tearing. The film is then cut into
narrow strips and wound on itself with an automatic fiber scroller, resulting in
a fiber that can be knotted and stretched without fracturing.
"We found this graphene oxide fiber was very
strong, much better than other carbon fibers. We believe that pockets of air
inside the fiber keep it from being brittle," says Mauricio Terrones, professor
of physics, chemistry and materials science and engineering at Penn State.
Terrones and colleagues believe this method opens up multiple possibilities for
useful products. For instance, removing oxygen from the GO fiber results in a
graphene fiber with high electrical conductivity. Adding silver nanorods to the
graphene film would increase the conductivity to the same as copper, which
could make it a much lighter weight replacement for copper transmission lines.
Many kinds of highly sensitive sensors are imaginable.
"The importance is that we can do almost any
material, and that could open up many avenues – it’s a lightweight material
with multifunctional properties," Terrones remarks. nd the main
ingredient, graphite, is mined and sold by the ton.
Their discovery was reported online in a recent
issue of ACS Nano and titled "Super-stretchable Graphene Oxide Macroscopic
Fibers with Outstanding Knotability Fabricated by Dry Film Scrolling."
(ACS Nano 2014, DOI: 10.1021/nn501098d) Penn State and Shinshu University have
applied for a joint patent on the process. The researchers received support
from the Research Center for Exotic Nanocarbons, Japan, and the Center for
Nanoscale Science, Penn State.
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